Phone: +7 (383) 330-67-71, Fax: +7 (383) 330-80-56, E-mail: bic@catalysis.ru
5 Lavrentiev Ave., 630090, Novosibirsk, Russia
Spectral Methods
Homogeneous and heterogeneous catalysts, reactions with their participation.
Bruker AVANCE-400 (magnetic field 9.4 T) and Bruker AVANCE-400/microtomograph (magnetic field 9.4 T) NMR spectrometers for liquid-state and solid-state spectroscopy with a representative set of probeheads for any applications:
1. Home-built high-temperature (up to 600°C) probeheads for studies of molten state.
2. High-speed probeheads MAS: 7 mm - for rotation frequency up
3. MAS experiments under controlled atmosphere conditions in sealed ampoules.
4. Solid – state NMR technique for quadrupolar nuclei with a half-integral spin:
Sample volume – from 0.1 to 5 cm3 depending on nucleus type.
Prof. E.P. Talsi. In situ NMR and EPR study of the structure and reactivity of the active intermediates in homogenous catalytic oxidation of alkanes and alkylbenzenes, olefines epoxidation and polimerization reactions.
Prof. M.A. Fedotov. NMR study of the coordinate compounds structure for molybdenum, tungsten and metals of platinum group in the solutions and their catalytic properties. The author of the monographs “Nuclear magnetic resonance in solutions of inorganic compounds” and “Nuclear magnetic resonance in inorganic chemistry”.
Prof. O.B. Lapina. Solid-state and high-temperature NMR studies of the structure and mechanism of formation of the active sites of heterogeneous catalysts.
Prof. A.G. Stepanov. Study of hydrocarbon conversion on solid catalysts, reactions mechanism and products analysis including in situ.
Dr. R.I. Maximovskaya. Structure and conversions of polyoxometallates in solutions according to the data of polynuclear NMR spectroscopy.
Dr. K.P. Bryliakov. Study of structure of intermediates in reactions of asymmetric oxidation.
Dr. D.A. Babushkin. NMR spectroscopy researches of intermediates in homogeneous catalytic reactions of oxidation and polymerization, determination of structure for organic, metalorganic and complex compounds, the analysis of functionalized polymers.